Test

Material Safety Data Sheet
PERMANONE® 30-30

SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION

Product name
MSDS Number
EPA Registration No.
Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 USA For MEDICAL, TRANSPORTATION or other EMERGENCY call: 1-800-334-7577 (24 hours/day) For Product Information call: 1-800-331-2867
SECTION 2. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Emergency Overview
Caution! Harmful if swallowed or absorbed through skin. Moderate eye irritation. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapour or mist. Physical State
Appearance

Exposure routes
Skin contact, Ingestion, Inhalation, Eye contact
Immediate Effects
Moderate eye irritation. Avoid contact with eyes. Causes skin irritation. Harmful if absorbed through skin. Avoid contact with skin Ingestion
Harmful if swallowed. Do not take internally. Inhalation
May be harmful if inhaled. Avoid inhalation of vapour or mist. Chronic or Delayed
This product or its components may have target organ effects. This product or its Long-Term
components may have long term (chronic) health effects. Potential Environmental
Highly toxic to bees. Extremely toxic to fish and aquatic invertebrates. Material Safety Data Sheet
PERMANONE® 30-30

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name
Average % by Weight

SECTION 4. FIRST AID MEASURES
When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately. Ingestion
Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Inhalation
Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Notes to physician
Treatment
Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote.
SECTION 5. FIRE FIGHTING MEASURES

Flash point
Suitable extinguishing
Carbon dioxide (CO2), Dry chemical, Foam, Water Material Safety Data Sheet
PERMANONE® 30-30
Fire Fighting
Keep out of smoke. Fight fire from upwind position. Cool closed containers Instructions
exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing.
SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled Methods for cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations. Additional advice
Use personal protective equipment. Do not allow to enter soil, waterways or
SECTION 7. HANDLING AND STORAGE

Handling procedures
Use only in area provided with appropriate exhaust ventilation. Handle and open container in a manner as to prevent spillage. Keep away from heat and sources of ignition. Storing Procedures
Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Store in original container and out of the reach of children, preferably in a locked storage area. Work/Hygienic
Wash hands thoroughly with soap and water after handling and before eating, Procedures
drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Min/Max Storage
Recommended minimum transport/storage temperature: 4 °C / 39 °F Temperatures

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

General Protection
Follow all label instructions. Train employees in safe use of the product. Material Safety Data Sheet
PERMANONE® 30-30
Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry. Eye/Face Protection
Hand protection
Chemical resistant nitrile rubber gloves Body Protection
Wear long-sleeved shirt and long pants and shoes plus socks. Respiratory protection
When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations. Exposure Limits
*OES BCS: Internal Bayer CropScience "Occupational Exposure Standard"
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Physical State
Bulk density

SECTION 10. STABILITY AND REACTIVITY

Incompatibility
Chemical Stability
Stable under recommended storage conditions.
SECTION 11. TOXICOLOGICAL INFORMATION

Only acute toxicity studies have been performed on this product as formulated. The non-acute information pertains to the two technical-grade active ingredients, permethrin and piperonyl butoxide. Material Safety Data Sheet
PERMANONE® 30-30

Acute oral toxicity
male/female combined rat: LD50: 993 mg/kg Acute dermal toxicity
Acute inhalation toxicity
Exposure time: 4 h Determined in the form of liquid aerosol. rat: LC50: > 8.8 mg/l Exposure time: 1 h Determined in the form of liquid aerosol. Extrapolated from the 4 hr LC50. Skin irritation
Eye irritation
Sensitisation
Chronic toxicity
Permethrin caused neurobehavioral effects (e.g., tremors) and/or organ effects (liver, lung, kidney) in chronic studies in rats, mice and dogs. Piperonyl butoxide caused decreased body weights and/or increased organ weights (liver, kidney, adrenal) in chronic studies in rats and dogs. Assessment Carcinogenicity
Permethrin has low oncogenic potential in mice and no oncogenic potential in rats, therefore, EPA has
concluded the likelihood of oncogenicity effects in humans from permethrin to be extremely low or
nonexistent.
Piperonyl butoxide gave no evidence of a carcinogenic potential in a lifetime feeding study in rats. In an
oncogenicity study in mice, piperonyl butoxide caused an increased incidence of liver tumors. The US EPA
has categorized piperonyl butoxide as a group C carcinogen, possible human carcinogen, based on limited
evidence of cancer in laboratory animals.
ACGIH
Reproductive toxicity
Permethrin was not a reproductive toxicant in multi-generation reproduction studies in rats. Material Safety Data Sheet
PERMANONE® 30-30
Piperonyl butoxide was not a reproductive toxicant in a two-generation study in rats. DEVELOPMENTAL TOXICITY: Permethrin was not a primary developmental toxicant in rats, mice and rabbits. Developmental effects (e.g., decreased fetal weights) were observed in rats and rabbits but were considered secondary to maternal toxicity. Piperonyl butoxide did not cause developmental, embryotoxic or teratogenic effects in developmental toxicity studies in rats and rabbits. Assessment
Permethrin caused neurobehavioral effects (e.g., tremors) in an acute and neurotoxicity
subchronic neurotoxicity screening study in rats without any correlating Piperonyl butoxide did not demonstrate the potential to cause neurotoxicity in standard toxicity studies submitted to the Agency. EPA has concluded that there is not a concern for neurotoxicity resulting from exposure to piperonyl butoxide. Mutagenicity
Permethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo Piperonyl butoxide does not have significant potential for mutagenicity based on sufficient evidence.
SECTION 12. ECOLOGICAL INFORMATION

Environmental
Do not apply when weather conditions favor runoff or drift. Drift and runoff from precautions
treated areas may be hazardous to aquatic organisms in adjacent sites. Do not allow to get into surface water, drains and ground water. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Apply this product as specified on the label. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area.
SECTION 13. DISPOSAL CONSIDERATIONS

General Disposal
Pesticide, spray mixture or rinse water that cannot be used according to label Guidance
instructions may be disposed of on site or at an approved waste disposal facility. Container Disposal
Triple rinse containers. Then offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill or incineration, or if allowed by State and Local authorities, by burning. If burned, stay out of smoke. Material Safety Data Sheet
PERMANONE® 30-30
RCRA Information
Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply.
SECTION 14. TRANSPORT INFORMATION

Not dangerous goods / not hazardous material
IMDG
UN-Number
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERMETHRIN, PIPERONYL BUTOXIDE SOLUTION)
IATA
UN-Number
Class 9
Packaging group
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERMETHRIN, PIPERONYL BUTOXIDE SOLUTION ) This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements. INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN POISON
SECTION 15. REGULATORY INFORMATION

EPA Registration No.

US Federal Regulations
TSCA list
US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)
SARA Title III - Section 302 - Notification and Information
SARA Title III - Section 313 - Toxic Chemical Release Reporting
US States Regulatory Reporting
CA Prop65
This product does not contain any substances known to the State of California to cause cancer. Material Safety Data Sheet
PERMANONE® 30-30
This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients

Canadian Regulations
Canadian Domestic Substance List

Environmental
Clean Water Section 307 Priority Pollutants
Safe Drinking Water Act Maximum Contaminant Levels

International Regulations
European Inventory of Existing Commercial Substances (EINECS)

SECTION 16. OTHER INFORMATION

NFPA 704 (National Fire Protection Association): 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: Updated due to new system and numbering scheme. Updated for general editorial purposes. Revision Date: 12/08/2010 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.

Source: http://www.backedbybayer.com/system/product/msds_en/55/Permanone_30-30_08Dec2010.pdf